⚗️ Class 12 Chemistry — Crash Revision 2026
CBSE 24 Feb Master Plan
Physical + Inorganic + Organic — Formulas, Reactions, Named Reactions
🎯 Chemistry = Formulas + Reactions + Named Reactions! Practice करो, रटो, numericals solve करो = marks पक्के!
📊 Section-wise Weightage — 70 marks (Theory)
Ch.1-3
Ch.8-9
Ch.10-14
Ch.4-5
Ch.6-7, Ch.16
⚗️ PHYSICAL CHEMISTRY — 23 marks
• Raoult's Law: PA = P°A × xA
• ΔTb = Kb × m (boiling point elevation)
• ΔTf = Kf × m (freezing point depression)
• π = CRT (osmotic pressure, C = molarity)
• Van't Hoff factor: i = (1 + (n-1)α) for dissociation
• Mole fraction: xA = nA/(nA + nB)
📷 +ve deviation (Acetone+CS₂): P > P°x | -ve deviation (Acetone+Chloroform): P < P°x
• E°cell = E°cathode - E°anode
• Nernst Equation: E = E° - (RT/nF)ln Q = E° - (0.0591/n)log Q (at 298K)
• ΔG° = -nFE°cell
• Conductivity: κ = (1/R) × (l/A) = G × G*
• Molar Conductivity: Λm = (κ × 1000)/M
• Kohlrausch's Law: Λ°m = ν+λ°+ + ν-λ°-
• Faraday's: m = (M × I × t)/(n × F), F = 96485 C/mol
📷 Daniel Cell + Nernst Equation — हर साल numerical आता है!
• Rate = k[A]n (rate law)
• Zero Order: [A] = [A]₀ - kt, t½ = [A]₀/2k
• First Order: k = (2.303/t) log([A]₀/[A]), t½ = 0.693/k
• Arrhenius: k = Ae-Ea/RT, ln(k₂/k₁) = (Ea/R)(1/T₁ - 1/T₂)
• Units of k: Zero = mol L⁻¹s⁻¹, First = s⁻¹, Second = L mol⁻¹s⁻¹
🧪 INORGANIC CHEMISTRY — 12 marks (Easy Scoring!)
🔑 Important Compounds:
- KMnO₄ (Potassium Permanganate) — preparation, properties, structure
- K₂Cr₂O₇ (Potassium Dichromate) — preparation, oxidising properties
- Cr₂O₇²⁻ ⇌ 2CrO₄²⁻ (pH dependent: acidic = orange, basic = yellow)
• Cu²⁺ = नीला (Blue) | Ni²⁺ = हरा (Green) | Co²⁺ = गुलाबी (Pink)
• Fe³⁺ = पीला-भूरा (Yellow-brown) | Fe²⁺ = हल्का हरा (Pale green)
• Mn²⁺ = हल्का गुलाबी (Pale pink) | Cr³⁺ = हरा (Green) | Zn²⁺ = रंगहीन (d¹⁰ — no d-d transition!)
📌 Reason: d-d transition → visible light absorb → complementary colour दिखता है। d⁰ & d¹⁰ = colourless (no transition possible)
• CFT: Δ₀ = 10Dq (octahedral), Δt = 4/9 Δ₀ (tetrahedral)
• Spectrochemical Series: I⁻ < Br⁻ < Cl⁻ < F⁻ < OH⁻ < H₂O < NH₃ < en < NO₂⁻ < CN⁻ < CO
• IUPAC naming: cation first, anion next; ligands alphabetical
• [Fe(CN)₆]⁴⁻ = Hexacyanoferrate(II), [Co(NH₃)₆]³⁺ = Hexaamminecobalt(III)
📷 Octahedral CFT splitting: t₂g (dxy, dxz, dyz) ↓ और eg (dx²-y², dz²) ↑
🔬 ORGANIC CHEMISTRY — 19 marks (Highest!)
• SN2: CH₃Br + OH⁻ → CH₃OH + Br⁻ (1° — backside attack, inversion)
• SN1: (CH₃)₃CBr → (CH₃)₃C⁺ → product (3° — racemisation)
• Wurtz: 2R-X + 2Na → R-R + 2NaX
• Sandmeyer: ArN₂⁺ + CuCl → ArCl (or CuBr → ArBr)
• Kolbe's Reaction: C₆H₅ONa + CO₂ + H₂O → Salicylic acid
• Reimer-Tiemann: Phenol + CHCl₃ + NaOH → Salicylaldehyde
• Williamson Synthesis: R-ONa + R'-X → R-O-R' (ether)
• Kolbe's Electrolysis: CH₃COONa → CH₃-CH₃ + CO₂
• Rosenmund Reduction: RCOCl + H₂/Pd-BaSO₄ → RCHO
• Stephen Reaction: RCN + SnCl₂/HCl → RCHO
• Aldol Condensation: 2CH₃CHO → CH₃CH(OH)CH₂CHO (β-hydroxy aldehyde)
• Cross Aldol: HCHO + CH₃CHO → HOCH₂CH₂CHO
• Cannizzaro: 2HCHO + NaOH → HCOONa + CH₃OH (disproportionation)
• Clemmensen Reduction: RCOR' + Zn-Hg/HCl → RCH₂R'
• Wolff-Kishner: RCOR' + NH₂NH₂/KOH → RCH₂R'
• HVZ (Hell-Volhard-Zelinsky): RCH₂COOH + Br₂/P → RCHBrCOOH
📷 ये Named Reactions रट लो = 8-10 marks guaranteed!
📷 Tollens' = Silver Mirror (Ag) | Fehling's = Red ppt (Cu₂O) | Iodoform = Yellow ppt (CHI₃) — ये 3 tests याद करो!
Everyday Life: Drugs (Analgesics, Antipyretics, Antibiotics, Antiseptics, Antifertility, Antihistamines, Tranquilizers), Chemicals in Food (Preservatives, Artificial sweeteners — Saccharin, Aspartame), Soaps vs Detergents (micelle formation)।
📅 6-Day Crash Plan — CBSE 24 Feb
📖 Notes → | 📖 Hindi →
📖 Electrochem → | 📖 Kinetics →
📖 d-block → | 📖 Coordination →
📖 Haloalkanes → | 📖 Alcohols →
📄 Printable Notes →
📚 सम्पूर्ण Study Material
📖 Chapter Notes
📝 Tests & Important Questions
❓ FAQ
📢 Chemistry CBSE 24 Feb — Share करो!
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